J/MNRAS/435/1198 z∼6 QSOs CIV doublet absorption systems (D'Odorico+, 2013) Metals in the IGM approaching the re-ionization epoch: results from X-shooter at the VLT. D'Odorico V., Cupani G., Cristiani S., Maiolino R., Molaro P., Nonino M., Centurion M., Cimatti A., Di Serego Alighieri S., Fiore F., Fontana A., Gallerani S., Giallongo E., Mannucci F., Marconi A., Pentericci L., Viel M., Vladilo G. =2013MNRAS.435.1198D ADC_Keywords: QSOs ; Spectroscopy Keywords: galaxies: abundances - intergalactic medium - quasars: absorption lines - cosmology: observations Abstract: We present the results of observations taken with the X-shooter spectrograph devoted to the study of quasars at z∼6. This paper focuses on the properties of metals at high redshift traced, in particular, by the CIV doublet absorption systems. Six objects were observed with resolutions ≃27 and 34km/s in the visual, and 37.5 and 53.5km/s in the near-infrared. We detected 102 CIV lines in the range: 4.35