Final reduced spectra used for the elemental abundance measurements. We observed both XO-2 components with the high resolution HARPS-N@TNG (R~115000, λ~3900-6900Å) spectrograph between November 20, 2012 and October 4, 2014. Solar spectra were also obtained through observations of the asteroid Vesta. The spectra reduction was obtained using the 2013 November version of the HARPS-N instrument data reduction software (DRS) pipeline. A detailed description of the observations and data reduction is reported in Paper II (Desidera et al., 2013A&A...554A..29D) <P />(2 data files). <P />