Please use this identifier to cite or link to this item:
http://hdl.handle.net/20.500.12386/30552
DC Field | Value | Language |
---|---|---|
dc.contributor.author | BIANCO, ANDREA | en_US |
dc.contributor.author | Ferrari, Giorgio | en_US |
dc.contributor.author | Castagna, Rossella | en_US |
dc.contributor.author | ROSSI, Andrea | en_US |
dc.contributor.author | Carminati, Marco | en_US |
dc.contributor.author | PARIANI, Giorgio | en_US |
dc.contributor.author | Tommasini, Matteo | en_US |
dc.contributor.author | Bertarelli, Chiara | en_US |
dc.date.accessioned | 2021-02-23T11:22:44Z | - |
dc.date.available | 2021-02-23T11:22:44Z | - |
dc.date.issued | 2016 | en_US |
dc.identifier.issn | 1463-9076 | en_US |
dc.identifier.uri | http://hdl.handle.net/20.500.12386/30552 | - |
dc.description.abstract | The dipole moment of photochromic diarylethenes is determined in solution for both the coloured and uncoloured forms by measuring the capacitance of a capacitor filled with a photochromic solution as a dielectric material. Diarylethenes with different substituents are investigated and the modulation of the dipole moment is related to their chemical structures. We determine a modulation of the dipole moment up to 4 Debye. We discuss the model used to obtain the dipole moment from the capacitance measurements and we compare the experimental results with the outcomes from DFT calculations. The results highlight the importance of conformational effects in the description of the dipole moment of diarylethenes. | en_US |
dc.language.iso | eng | en_US |
dc.title | Light-induced dipole moment modulation in diarylethenes: a fundamental study | en_US |
dc.type | Article | - |
dc.identifier.doi | 10.1039/C6CP05609A | en_US |
dc.identifier.scopus | 2-s2.0-85029645141 | en_US |
dc.identifier.isi | 000388943500032 | en_US |
dc.identifier.url | https://pubs.rsc.org/en/content/articlelanding/2016/CP/C6CP05609A#!divAbstract | en_US |
dc.relation.medium | STAMPA | en_US |
dc.relation.volume | 18 | en_US |
dc.relation.issue | 45 | en_US |
dc.relation.firstpage | 31154 | en_US |
dc.relation.lastpage | 31159 | en_US |
dc.type.referee | REF_1 | en_US |
dc.description.international | no | en_US |
dc.relation.scientificsector | FIS/01 - FISICA SPERIMENTALE | en_US |
dc.relation.journal | PHYSICAL CHEMISTRY CHEMICAL PHYSICS | en_US |
dc.type.miur | 262 Articolo in rivista | - |
dc.identifier.adsbibcode | 2016PCCP...1831154B | en_US |
dc.relation.ercsector | ERC sectors::Physical Sciences and Engineering::PE4 Physical and Analytical Chemical Sciences: Analytical chemistry, chemical theory, physical chemistry/chemical physics | en_US |
dc.description.apc | no | en_US |
dc.description.oa | 1 – prodotto con file in versione Open Access (allegare il file al passo 5-Carica) | en_US |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.openairetype | Article | - |
item.languageiso639-1 | en | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
item.fulltext | With Fulltext | - |
crisitem.author.dept | O.A. Brera | - |
crisitem.author.dept | O.A. Brera | - |
crisitem.author.orcid | 0000-0002-7691-404X | - |
crisitem.author.orcid | 0000-0003-3724-7667 | - |
crisitem.journal.journalissn | 1463-9076 | - |
crisitem.journal.ance | E131771 | - |
Appears in Collections: | 1.01 Articoli in rivista |
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