Lusso, E.E.LussoRisaliti, G.G.RisalitiNARDINI, EMANUELEEMANUELENARDINIBargiacchi, G.G.BargiacchiBenetti, M.M.BenettiBisogni, SusannaSusannaBisogniCapozziello, S.S.CapozzielloCivano, F.F.CivanoEggleston, L.L.EgglestonElvis, M.M.ElvisFabbiano, G.G.FabbianoGILLI, RobertoRobertoGILLIMarconi, AlessandroAlessandroMarconiPaolillo, MaurizioMaurizioPaolilloPiedipalumbo, E.E.PiedipalumboSALVESTRINI, FrancescoFrancescoSALVESTRINISignorini, M.M.SignoriniVignali, C.C.Vignali2022-06-172022-06-1720200004-6361http://hdl.handle.net/20.500.12386/32375We present a new catalogue of ˜2400 optically selected quasars with spectroscopic redshifts and X-ray observations from either Chandra or XMM-Newton. The sample can be used to investigate the non-linear relation between the ultraviolet (UV) and X-ray luminosity of quasars as well as to build a Hubble diagram up to a redshift of z ˜ 7.5. We selected sources that are neither reddened by dust in the optical and UV nor obscured by gas in the X-rays, and whose X-ray fluxes are free from flux-limit-related biases. After checking for any possible systematics, we confirm, in agreement with our previous works, that the X-ray to UV relation provides distance estimates matching those from supernovae up to z ˜ 1.5, and its slope shows no redshift evolution up to z ˜ 5. We provide a full description of the methodology for testing cosmological models, further supporting a trend whereby the Hubble diagram of quasars is well reproduced by the standard flat cold dark matter model up to z ˜ 1.5-2, but strong deviations emerge at higher redshifts. Since we have minimised all non-negligible systematic effects and proven the stability of the L<SUB>X</SUB> - L<SUB>UV</SUB> relation at high redshifts, we conclude that an evolution of the expansion rate of the Universe should be considered as a possible explanation for the observed deviation, rather than some systematic (redshift-dependent) effect associated with high-redshift quasars. <P />Full Table 3 is only available at the CDS via anonymous ftp to <A href="http://cdsarc.u-strasbg.fr/">http://cdsarc.u-strasbg.fr</A> (ftp://130.79.128.5) or via <A href="http://cdsarc.u-strasbg.fr/viz-bin/cat/J/A+A/642/A150">http://cdsarc.u-strasbg.fr/viz-bin/cat/J/A+A/642/A150</A>STAMPAenArticle10.1051/0004-6361/2020388992-s2.0-85093947185https://arxiv.org/abs/2008.08586https://www.aanda.org/articles/aa/full_html/2020/10/aa38899-20/aa38899-20.html2020A&A...642A.150LFIS/05 - ASTRONOMIA E ASTROFISICAERC sectors::Physical Sciences and Engineering