Sugimura, K.K.SugimuraCoppola, C. M.C. M.CoppolaOmukai, K.K.OmukaiGALLI, DanieleDanieleGALLIPalla, F.F.Palla2020-06-222020-06-2220160035-8711http://hdl.handle.net/20.500.12386/26163We investigate the role of the H2+ channel on H2 molecule formation during the collapse of primordial gas clouds immersed in strong radiation fields which are assumed to have the shape of a diluted blackbody spectra with temperature Trad. Since the photodissociation rate of H2+ depends on its level population, we take full account of the vibrationally resolved H2+ kinetics. We find that in clouds under soft but intense radiation fields with spectral temperature Trad ≲ 7000 K, the H2+ channel is the dominant H2 formation process. On the other hand, for harder spectra with Trad ≳ 7000 K, the H- channel takes over H2+ in the production of molecular hydrogen. We calculate the critical radiation intensity needed for supermassive star formation by direct collapse and examine its dependence on the H2+ level population. Under the assumption of local thermodynamic equilibrium (LTE) level population, the critical intensity is underestimated by a factor of a few for soft spectra with Trad ≲ 7000 K. For harder spectra, the value of the critical intensity is not affected by the level population of H2+. This result justifies previous estimates of the critical intensity assuming LTE populations since radiation sources like young and/or metal-poor galaxies are predicted to have rather hard spectra.STAMPAenArticle10.1093/mnras/stv26552-s2.0-84959577029000368010000054https://academic.oup.com/mnras/article/456/1/270/10678422016MNRAS.456..270SFIS/05 - ASTRONOMIA E ASTROFISICA