Phosphorus-bearing Molecules in Massive Dense Cores

Abstract

Phosphorus is a crucial element for the development of life, but so far P-bearing molecules have been detected only in a few astrophysical objects; hence, its interstellar chemistry is almost totally unknown. Here, we show new detections of phosphorus nitride (PN) in a sample of dense cores in different evolutionary stages of the intermediate- and high-mass star formation process: starless, with protostellar objects, and with ultracompact H II regions. All detected PN line widths are smaller than ≃5 km s<SUP>-1</SUP>, and they arise from regions associated with kinetic temperatures smaller than 100 K. Because the few previous detections reported in the literature are associated with warmer and more turbulent sources, the results of this work show that PN can arise from relatively quiescent and cold gas. This information is challenging for theoretical models that invoke either high desorption temperatures or grain sputtering from shocks to release phosphorus into the gas phase. Derived column densities are of the order of 10<SUP>11-12</SUP> cm<SUP>-2</SUP>, marginally lower than the values derived in the few high-mass star-forming regions detected so far. New constraints on the abundance of phosphorus monoxide, the fundamental unit of biologically relevant molecules, are also given. <P />Based on observations carried out with the IRAM-30 m Telescope. IRAM is supported by INSU/CNRS (France), MPG (Germany), and IGN (Spain).